– 近五年代表作（部分） –

ORCID识别号: https://orcid.org/0000-0003-4611-2094

(101) Wang, L. N.; Jiang, X.; Trabelsi, T.; Wang, G. J.; Francisco, J. S.; Zeng, X. Q.; Zhou, M. F. J. Am. Chem. Soc. 2024, Accepted article.

(100) Xue, J. F.; Shao, X.; Li, J.; Li, J.; Trabelsi, T.; Francisco, J. S.; Zeng, X. Q. J. Am. Chem. Soc. 2024, Accepted article.

(99) Chen, X. L.; Wang, G. J.; Zeng, X. Q.; Li, W. X.; Zhou, M. F. J. Am. Chem. Soc. 2024, 146, 1484-1490.

(98) Jiang, X.; Wang, L. N.; Rauhut, G.; Li, X. L.; Hong, J. L.; Zhou, M. F.; Zeng, X. Q. MNRAS, 2024, 527, 8996-9003.

(97) Lu, B.; Zeng, X. Q. Chem. Eur. J. 2023, doi.org/10.1002/chem.202303283.

(96) Zhu, B. F.; Zeng, X. Q. J. Chem. Phys. A 2023, 127, 10591-10599.

(95) Shao, X.; Wu, Z.; Wang, L. N.; Rauhut, G.; Zeng, X. Q. J. Phys. Chem. Lett. 2023, 14, 10450-10456.

(94) Xue, J. F.; Shao, X.; Jiang, X.; Zeng, X. Q. Phys. Chem. Phys. Chem. 2023, 25, 18166-18174

(93) Li, W. X.; Pérez, C.; Steber, A. L.; Schnell, M.; Lv, D. D.; Wang, G. J.; Zeng, X. Q.; Zhou, M. F. J. Am. Chem. Soc. 2023, 145, 4119-4128.

(92) Zhou,Y. Y.; Fang, W.; Wang, L. N.; Zeng, X. Q.; Zhang, D. H.; Zhou, M. F. J. Am. Chem. Soc. 2023, 145, 8817−8821.

(91) Jiang, J. J.; Lu, B.; Zhu, B. F.; Li, X. L.; Rauhut, G.; Zeng, X. Q. J. Phys. Chem. Lett. 2023, 14, 4327−4333.

(90) Li, X. L.; Lu, B.; Jiang, J. J.; Wang, L. N.; Trabelsi, T.; Francisco, J. S.; Fang, W.; Zhou, M. F.; Zeng, X. Q. J. Am. Chem. Soc. 2023, 145, 1982−1987.

(89) Li, X. X.; Lu, B.; Wang, L. N.; Xue, J. F.; Zhu, B. F.; Trabelsi, T.; Francisco, J. S.; Zeng, X. Q. Nat. Commun. 2022, 12, 7150.

(88) Lu, B.; Shao, X.; Jiang, X.; Xue, J. F.; Rauhut, G.; Tan, G. W.; Fang, W.; Zeng, X. Q. J. Am. Chem. Soc. 2022, 144, 21853−21857.

(87) Lu, B.; Wang, L. N.; Jiang, X.; Rauhut, G.; Zeng, X. Q. Angew. Chem. Int. Ed. 2023, doi.org/10.1002/anie.202217353

(86) Wang, L. N.; Li, X. L.; Jiang, X.; Zeng, X. Q.; Zhou, M. F. J. Phys. Chem. Lett. 2022, 13, 2619−2624.

(85) Wu, Z.; Shao, X.; Zhu, B. F.; Wang, L. N.; Lu, B.; Trabelsi, T.; Francisco, J. S.; Zeng, X. Q. Commun. Chem. 2022, 5, 19.

(84) Zhu, B. F.; Jiang, J. J.; Lu, B.; Li, X. L.; Jiang, X.; Rauhut, G.; Zeng, X. Q. Chem. Commun. 2022, 58, 10703-10706.

(83) Wang, L. N.; Pan, S.; Wang, G. J.; Zeng, X. Q.; Zhou, M. F.; Frenking, G. Chem. Commun. 2022, 58, 8532-8535.

(82) Wang, L. N.; Wu, Z.; Lu, B.; Zeng, X. Q. J. Environ. Sci. 2022, 114, 160-169.

(81) Wang, L. N.; Jiang, X.; Wang, G. J.; Zeng, X. Q.; Zhou, M. F. Chem. Eur J. 2022, doi.org/10.1002/chem.202203704

(80) Zhu, B. F.; Wu, Z.; Wang, L. N.; Lu, B.; Trabelsi, T.; Francisco, J. S.; Zeng, X. Q. Chem. Commun. 2021, 57, 12143-12146.

(79) Zhu, B. F.; Jiang, J. J.; Lu, B.; Li, X. L.; Zeng, X. Q. Phys. Chem. Chem. Phys. 2022, 24, 8881-8889.

(78) Lu, B.; Jiang, X.; Zeng, X. Q. Phys. Chem. Chem. Phys. 2022, 24, 17673-17678.

(77) Jiang, J. J.; Zhu, B. F.; Jiang, X.; Lu, B.; Zeng, X. Q. Phys. Chem. Chem. Phys. 2022, 24, 20828-20836.

(76) Wu, Z.; Zeng, X. Q. J. Phys. Chem. A 2022, 126, 4367-4375.

(75) Lu, B.; Trabelsi, T.; Esposito, V. J.; Fortenberry, R. C.; Francisco, J. S.; Zeng, X. Q. J. Phys. Chem. A 2021, 125, 10615−10621.

Bif Jiangeng Zhu,

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(74) Chu, X. X.; Qian, W. Y.; Lu, B.; Wang, L. N.; Qin, L.; Li, J.; Rauhut, G.; Trabelsi, T.; Francisco, J. S.; Zeng, X. Q. Angew. Chem. Int. Ed. 2020, 59, 21949-21953.

(73) Chen, C. Y.; Lu, B.; Zhao, X. F.; Qian, W. Y.; Liu, J.; Trabelsi, T.; Francisco, J. S.; Qin, J.; Li, J.; Wang, L. N.; Zeng, X. Q. J. Am. Chem. Soc. 2020, 142, 2175-2179.

(72) Qin, Y. Y.; Lu, B.; Rauhut, G.; Song, C.; Chu, X. X.; Wang, L. N.; Zeng, X. Q. Angew. Chem. Int. Ed. 2019, 58, 17277-17281.

(71) Zhao, X. F.; Chu, X. X.; Rauhut, G.; Chen, C. Y.; Song, C.; Lu, B.; Zeng, X. Q. Angew. Chem. Int. Ed. 2019, 58, 12164-12169.

(70) Wu, Z.; Chen, C. Y.; Liu, J.; Lu, Y.; Xu, J.; Liu, X. Y.; Cui, G. L.; Trabelsi, T.; Francisco, J. S.; Mardyukov, A.; Eckhardt, A. K.; Schreiner, P. R.; Zeng, X. Q. J. Am. Chem. Soc. 2019, 141, 3361−3365.

(69) Chu, X. X.; Yang, Y.; Lu, B.; Wu, Z.; Qian, W. Y.; Song, C.; Xu, X. F.; Abe, M.; Zeng, X. Q. J. Am. Chem. Soc. 2018,140, 13604-13608.

(68) Xu, J.; Wu, Z.; Wan, H. B.; Deng, G. H.; Lu, B.; Eckhardt, A. K.; Schreiner, P. R.; Trabelsi, T.; Francisco, J. S.; Zeng, X. Q. J. Am. Chem. Soc. 2018, 140, 9972-9978.

(67) Dong, X. L.; Deng, G. H.; Wu, Z.; Xu, J.; Lu, B.; Trabelsi, T.; Francisco, J. S.; Zeng, X. Q. Angew. Chem. Int. Ed. 2018, 57, 7513-7517.

(66) Wu, Z.; Feng, R. J.; Xu, J.; Lu, Y.; Lu, B.; Yang, T.; Frenking, G.; Trabelsi, T.; Francisco, J. S.; Zeng, X. Q. J. Am. Chem. Soc. 2018, 140, 1231-1234.

(65) Feng, R. J.; Lu, Y.; Deng, G. H.; Xu, J.; Wu, Z.; Li, H. M.; Liu, Q.; Kadowaki, N.; Abe, M.; Zeng, X. Q. J. Am. Chem. Soc. 2018, 140, 10-13.

(64) Chu, X. X.; Song, C.; Yang, Y.; Zeng, X. Q. Oxidation of a phosphinidene oxide: formation of a dioxaphosphirane oxide with oxygen scrambling. Chem. Commun. 2019, 55, 245--248.

(63) Liu, Q.; Wan, H. B.; Lu, Y.; Lu, B.; Zeng, X. Q. Photodecomposition of 1H-Pyrrole Carbonyl Azides: Direct Observation of Singlet 1H-Pyrrole Carbonyl Nitrenes and Triplet 1H-3-Pyrrylnitrene. Eur. J. Org. Chem. 2019, 401-411.

(62) Feng, R. J.; Lu, Y.; Deng, G. H.; Xu, J.; Wu, Z.; Li, H. M.; Liu, Q.; Kadowaki, N.; Abe, M.; Zeng, X. Q. Magnetically Bistable Nitrenes: Matrix Isolation of Furoylnitrenes in Both Singlet and Triplet States and Triplet 3-Furylnitrene. J. Am. Chem. Soc. 2018, 140, 10-13.

(61) Wu, Z.; Feng, R. J.; Xu, J.; Lu, Y.; Lu, B.; Yang, T.; Frenking, G.; Trabelsi, T.; Francisco, J. S.; Zeng, X. Q. Photoinduced Sulfur−Nitrogen Bond Rotation and Thermal Nitrogen Inversion in Heterocumulene OSNSO. J. Am. Chem. Soc. 2018, 140, 1231-1234.

(60) Xu, J.; Wu, Z.; Wan, H. B.; Deng, G. H.; Lu, B.; Eckhardt, A. K.; Schreiner, P. R.; Trabelsi, T.; Francisco, J. S.; Zeng, X. Q. Phenylsulfinyl Radical: Gas-Phase Generation, Photoisomerization, and Oxidation. J. Am. Chem. Soc. 2018, 140, 9972-9978.

(59) Chu, X. X.; Yang, Y.; Lu, B.; Wu, Z.; Qian, W. Y.; Song, C.; Xu, X. F. Abe, M.; Zeng, X. Q. Methoxyphosphinidene and Isomeric Methylphosphinidene Oxide J. Am. Chem. Soc. 2018, 140, 13604−13608.

(58) Dong, X. L.; Deng, G. H.; Wu, Z.; Xu, J.; Lu, B.; Trabelsi, T.; Francisco, J. S.; Zeng, X. Q. Spectroscopic Identification of H2NSO and syn-and anti-HNSOH Radicals. Angew. Chem. Int. Ed. 2018, 57, 7513-7517.

(57) Lu, Y.; Li, H. M.; Abe, M.; Begue, D.; Wan, H. B.; Deng, G. H.; Xu, J.; Liu, K.; Zeng, X. Q. Sulfamoyl nitrenes: singlet or triplet ground state? Chem. Commun. 2018, 54, 6136--6139.

(56) Wu, Z.; Lu, B.; Feng, R. J.; Xu, J.; Lu, Y.; Wan, H. B.; Eckhardt, A. K.; Schreiner, P. R.; Xie, C. J; Guo, H.; Zeng, X. Q. Capture of SO3 isomers in the oxidation of sulfur monoxide with molecular oxygen. Chem. Commun. 2018, 54, 1690-1693.

(55) Wu, Z.; Wan, H. B.; Xu, J.; Lu, B.; Lu, Y.; Eckhardt, A. K.; Schreiner, P. R.; Xie, C. J.; Guo, H.; Zeng, X. Q. The Near-UV Absorber OSSO and Its Isomers. Chem. Commun. 2018, 54, 4517-4520.

(54) Lu, Y.; Li, H. M.; Abe, M.; Begue, D.; Wan, H. B.; Deng, G. H.; Xu, J.; Liu, K.; Zeng, X. Q. Sulfamoyl nitrenes: singlet or triplet ground state? Chem. Commun. 2018, 54, 6136--6139.

(53) Wu, Z.; Song, C.; Liu, J.; Lu, B.; Lu, Y.; Trabelsi, T.; Francisco, J. S.; Zeng, X. Q. Photochemistry of OPN: Formation of Cyclic PON and Reversible Combination with Carbon Monoxide. Chem. Eur. J. 2018, 24, 14627-14630.

(52) Wu, Z.; Xu, J.; Deng, G. H.; Chu, X. X.; Sokolenko, L.; Trabelsi, T.; Francisco, J. S.; Eckhardt, A. K.; Zeng, X. Q.; Schreiner, P. R. The Trifluoromethyl Sulfinyl And Oxathiyl Radicals. Chem. Eur J. 2018, 24, 1505-1508.

(51) Yang, Y.; Chu, X. X.; Lu, Y.; Abe, M.; Zeng, X. Q. Chloro- and Dichloro-methylsulfonyl Nitrenes: Spectroscopic Characterization, Photoisomerization, and Thermal Decomposition. Molecules 2018, 23, 3312.

(50) Dong, X. L.; Deng, G. H.; Xu, J.; Li, H.M.; Zeng, X. Q.; Decomposition of Sulfonyl Azide Isocyanate and Sulfonyl Diazide: The Oxygen-Shifted Curtius Rearrangement via Sulfonyl Nitrenes. J. Phys. Chem. A 2018, 122, 8511−8519.

(49) Feng, R. J.; Wu, Z.; Zeng, X. Q. Synthesis, conformation, and photochemistry of difluoroacetylisocyanate CF2HC(O)NCO and isothiocyanate CF2HC(O)NCS. J. M. S. 2018, 1172, 25-32.

(48) Wu, Z.; Liu, Q. F.; Xu, J.; Sun, H. L.; Li, D. Q.; Song, C.; Andrada, D. M. A.; Frenking, G.; Trabelsi, T.; Francisco, J. S.; Zeng, X. Q. Heterocumulene Sulfinyl Radical OCNSO. Angew. Chem. Int. Ed. 2017, 56, 2140-2144.

(47) Wu, Z.; Feng, R. J.; Li, H. M.; Xu, J.; Deng, G. H.; Abe, M.; Bégué, D.; Liu, K.; Zeng, X. Q. Fast Heavy-Atom: Tunneling in Trifluoroacetyl Nitrene. Angew. Chem. Int. Ed. 2017, 56, 15672-15676.

(46) Wu, Z.; Liu, Q. F.; Li, D. Q.; Feng, R. J.; Zeng, X. Q. Flash Vacuum Pyrolysis of Methoxysulfinyl Azide: Stepwise Decomposition via Methoxysulfinyl Nitrene. J. Anal. Appl. Pyrol. 2017, 124, 610-617.

(45) Feng, R. J.; Wu, Z.; Xu, J.; Liu, Q. F.; Zeng, X. Q. Difluoroacetyl Azide: Synthesis, Characterization, and Decomposition. J. Anal. Appl. Pyrol. 2017, 125, 209-217.

(44) Li, H. M.; Wu, Z.; Li, D. Q.; Wan, H. B.; Xu, J.; Abe, M; Zeng, X. Q. Direct Observation of Methoxycarbonylnitrene. Chem. Commun. 2017, 53, 4783-4786.

(43) Liu, Q. F.; Wu, Z.; Xu, J.; Lu, Y.; Li, H. M.; Zeng, X. Q. Methoxysulfinyl Radical CH3OSO: Gas-Phase Generation, Photochemistry, and Oxidation. J. Phys. Chem. A. 2017, 121, 3818–3825.

(42) Wu, Z.; Xu, J.; Liu, Q. F.; Dong, X. L.; Li, D. Q.; Holzman, N.; Frenking, G.; Trabelsi, T.; Francisco, J. S.; Zeng, X. Q. The Hypothiocyanite Radical OSCN and Isomers. Phys. Chem. Chem. Phys. 2017, 19, 16713-16720.

(41) Wan, H. B.; Li, H. M.; Xu, J.; Wu, Z.; Liu, Q. F.; Chu, X. X.; Abe, M.; Bégué, D.; Zeng, X. Q. N-Methylcarbamoyl Azide: Spectroscopy, X-ray Structure and Decomposition via Methylcarbamoyl Nitrene. Org. Chem. Front. 2017, 4, 1839-1848.

(40) Deng, G. H.; Dong, X. L.; Liu, Q. F.; Li, D. Q.; Li, H. M.; Sun, Q.; Zeng, X. Q. The Decomposition of Benzenesulfonyl Azide: A Matrix Isolation and Computational Study. Phys. Chem. Chem. Phys. 2017, 19, 3792-3799.

(39) Wu, Z.; Xu, J.; Sokolenko, L.; Yagupolskii, Y. L.; Feng, R. J.; Liu, Q.; Lu, Y.; Zhao, L. L.; Fernandez, I.; Frenking, G.; Trabelsi, T.; Francisco, J. S.;Zeng, X. Q. Parent Thioketene S-Oxide H2CCSO: Gas-Phase Generation, Structure, and Bonding Analysis. Chem. Eur. J. 2017, 23, 16566-16573.

(38) Wan, H. B.; Xu, J.; Liu, Q.; Li, H. M.; Lu, Y.; Abe, M.; Zeng, X. Q.; Contrasting Photolytic and Thermal Decomposition of PhenylAzidoformate: the Curtius Rearrangement Versus Intramolecular C-H Amination. J. Phys. Chem. A. 2017, 121, 8604-8613.

(37) Deng, G. H.; Wu, Z.; Li, D. Q.; Linguerri, R.; Francisco, J. S.; Zeng, X. Q. Simplest N-Sulfonylamine HNSO2. J. Am. Chem. Soc. 2016, 138, 11509-11512.

(36) Wu, Z.; Li, D. Q.; Li, H. M.; Zhu, B. F.; Sun, H. L.; Francisco, J. S.; Zeng, X. Q. Gas-Phase Generation and Decomposition of a Sulfinylnitrene into the Iminyl Radical OSN. Angew. Chem. Int. Ed. 2016, 55, 1507-1510.

(35) Zeng, X. Q. Angew. Chem. Int. Ed. 2016, 55, 8160.

(34) Liu, Q. F.; Li, H. M.; Wu, Z.; Li, D. Q.; Beckers, H.; Rauhut, G.; Zeng, X. Q. Photolysis of Carbonyl Diisocyanate: Generation of Isocyanatocarbonyl Nitrene and Diazomethanone. Chem. Asian. J. 2016, 11, 2953-2959.

(33) Li, H. M.; Wan, H. B.; Wu, Z.; Li, D. Q.; Bégué, D.; Wentrup, C.; Zeng, X. Q. Direct Observation of the Carbamoylnitrenes. Chem. Eur. J. 2016, 22, 7856-7862.

(32) Li, D. Q.; Schwabedissen, J.; Stammler, H. G.; Mitzal, N. W.; Willner, H.; Zeng, X. Q. Dichlorophosphanyl Isocyanate-Spectroscopy, Conformation and Molecular Structure in the Gas Phase and the Solid State. Phys. Chem. Chem. Phys. 2016, 18, 26245-26253.

(31) Deng, G. H.; Li, D. Q.; Wu, Z.; Li, H. M.; Bernhardt, E.; Zeng, X. Q. Methanesulfonyl Azide: Molecular Structure and Photolysis in Solid Noble Gas Matrices. J. Phys. Chem. A. 2016, 120, 5590-5597.

(30) Li, H. M.; Wu, Z.; Li, D. Q.; Zeng, X. Q.; Beckers, H.; Francisco,J. S. A Singlet Thiophosphoryl Nitrene and Its Interconversion with Thiazyl and Thionitroso Isomers. J. Am. Chem. Soc. 2015, 137, 10942-10945.

(29) Zhu, B. F.; Zeng, X. Q.; Beckers, H.; Francisco, J. S.; Willner, H. The Methylsulfonyloxyl Radical, CH3SO3. Angew. Chem. Int. Ed. 2015, 54, 11404-11408.

(28) Zeng, X. Q.; Antognini, A. F.; Beckers, H.; Willner, H. Isomers of Disulfur Dinitride, S2N2. Angew. Chem. Int. Ed. 2015, 54, 2758-2761.

(27) Sun, H. L.; Zhu, B. F.; Wu, Z.; Zeng, X. Q.; Beckers, H.; Jenkers, W. S. Thermally Persistent Carbonyl Nitrene: FC(O)N. J. Org. Chem. 2015, 80, 2006-2009.

(26) Zeng, X. Q.; Li, H. M.; Sun, H. L.; Beckers, B.; Willner, H.; Schaefer III, H. F. SN2P2 : A Neutral Five-Membered Sulfur-Pnictogen(III) Ring. Angew. Chem. Int. Ed. 2015, 54, 1327–1330.

(25) Wu, Z.; Li, H. M.; Zhu, B. F.; Zeng, X. Q.; Hayes, S. A.; Mitzel, N. W.; Beckers, H.; Berger, R. J. F. Conformational Composition, Molecular Structure and Decomposition of Difluorophosphoryi Azide in the Gas Phase. Phys. Chem. Chem. Phys. 2015, 17, 8784-8791.

(24) Li, D. Q.; Li, H. M.; Zhu, B. F.; Zeng, X. Q.; Willner, H.; Beckers, H.; Neuhaus, P.; Grote, D.; Sander, W.Decomposition of Fluorophosphoryl Diazide: A Joint Experimental and Theoretical Study. Phys. Chem. Chem. Phys. 2015, 17, 6433-6439.

(23) Li, H. M.; Li, D. Q.; Zeng, X. Q.; Liu, K.; Beckers, H.; Schaefer III, H. F.; Esselman, B. J.; McMahon, R. J. Toward Understanding the Decomposition of Carbonyl Diazide (N3)2C=O and Formation of Diazirinone cycl-N2CO: Experiment and Computations. J. Phys. Chem. A. 2015, 119, 8903-8911.

(22) Zeng, X. Q.; Beckers, H.; Willner, H.; Neuhaus, P.; Grote, D.; Sander, W. Photochemistry of Matrix Isolated (Trifluoromethyl)sulfonylAzide, CF3SO2N3. J. Phys. Chem. A 2015, 119, 2281-2288.

(21) Zeng, X. Q.; Beckers, H.; Seifert, J.; Banert, K. The Photochemical and Thermal Decomposition of Azidoacetylene in the Gas Phase, Solid Matrix, and Solutions. Eur. J. Org. Chem. 2014, 4077-4082.

(20) Zeng, X. Q.; Beckers, H.; Willner, H. The IminylRadical O2SN. Angew. Chem. Int. Ed. 2013, 52, 7981-7984.

(19) Zeng, X. Q.; Beckers, H.; Willner, H. Thermally Persistent Fluorosulfonyl Nitrene and Unexpected Formation of Fluorosulfonyl Radical. J. Am. Chem. Soc. 2013, 135, 2096-2099.

(18) Zeng, X. Q.; Bernhardt, E.; Beckers, H.; Banert, K.; Hagedorn, M.; Liu, H. FormylAzide: Properties and Solid-State Structure. Angew. Chem. Int. Ed. 2013, 52, 3503-3506.

(17) Zeng, X. Q.; Beckers, H.; Willner, H.; Francisco, J. S. Experimental Observation of the 16-electron SPN, SNP, and Cyclic PSN. Angew. Chem. Int. Ed. 2012, 51, 3334-3339.

(16) Zeng, X. Q.; Beckers, H.; Willner, H.; Stanton, J. F. Fascinating Diazirinone (N2CO), A Violet Gas. Eur. J. Inorg. Chem. 2012, 3403-3409.

(15) Zeng, X. Q.; Beckers, H.; Neuhaus, P.; Grote, D.; Sander, W. Elusive Fluorosulfinyl Nitrite Produced by Photolysis of Matrix-Isolated FS(O)2N. Z. Anorg. Allg. Chem. 2012, 638, 526–533.

(14) Zeng, X. Q.; Beckers, H.; Willner, H. Elusive O═P≡N, A Rare Example of Phosphorus σ2λ5-Coordination. J. Am. Chem. Soc. 2011, 133, 20696-20699.

(13) Zeng, X. Q.; Beckers, H.; Willner, H.; Stanton, J. F. Elusive Diazirinone, N2CO. Angew. Chem. Int. Ed. 2011, 50, 1720-1723.

(12) Zeng, X. Q.; Beckers, H.; Willner, H. Matrix Isolation of Two Isomers of N4CO. Angew. Chem. Int. Ed. 2011, 50, 482-485.

(11) Zeng, X. Q.; Beckers, H.; Willner, H.; Grote, D.; Sander, W. The Missing Link: Triplet Fluorocarbonylnitrene FC(O)N. Chem. Eur. J. 2011, 17, 3977-3984.

(10) Zeng, X. Q.; Beckers, H.; Bernhardt, E.; Willner, H. Synthesis and Characterization of Sulfuryldiazide, O2S(N3)2. Inorg. Chem. 2011, 50, 8679-8684.

(9) Zeng, X. Q.; Bernhardt, E.; Beckers, H.; Willner, H. Synthesis and Characterization of the Phosphorus Triazides OP(N3)3 and SP(N3)3. Inorg. Chem. 2011, 50, 11235-11241.

(8) Zeng, X. Q.; Beckers, H.; Willner, H.; Berger, R. J. F.; Hayes, S. A.; Mitzel, N. Structure and Conformational Properties of Azido(Difluoro)Phosphane, F2PN3. Eur. J. Inorg. Chem. 2011, 895-905.

(7) Zeng, X. Q.; Gerken, M.; Beckers, H.; Willner, H. AnomericEffects in Sulfonyl Compounds: An Experimental and Computational Study of Fluorosulfonylazide, FSO2N3, and Trifluoromethylsulfonylazide, CF3SO2N3. J. Phys. Chem. A. 2010, 114, 7624-7630.

(6) Zeng, X. Q.; Beckers, H.; Willner, H.; Lehmann, C. W. Bis(methanesulfonyl) Peroxide, CH3S(O)2OOS(O)2CH3: Spectroscopic, Structural, and Thermal Properties. Z. Anorg. Allg. Chem. 2010, 636, 2447-2453.

(5) Zeng, X. Q.; Gerken, M.; Beckers, H.; Willner, H. Synthesis and Characterization of Carbonyl Diazide, OC(N3)2. Inorg. Chem. 2010, 49, 9694-9699.

(4) Zeng, X. Q.; Gerken, M.; Beckers, H.; Willner, H. Spectroscopic and Structural Studies of Difluorophosphoryl Azide F2P(O)N3, Difluorophosphoryl Isocyanate F2P(O)NCO, and DifluorophosphoricAcidAnhydride, F2(O)POP(O)F2. Inorg. Chem. 2010, 49, 3002-3010.

(3) Zeng, X. Q.; Beckers, H.; Willner, H. Difluoro-λ5-Phosphinonitrile F2P≡N: Matrix Isolation and Photoisomerization into FP=NF. Angew. Chem. Int. Ed. 2009, 48, 4828-4831.

(2) Zeng, X. Q.; Beckers, H.; Willner, H.; Neuhaus, P.; Grote, D.; Sander, W. Difluorophosphorylnitrene, F2P(O)N: Matrix Isolationand Unexpected Rearrangement to F2PNO. Chem. Eur. J. 2009, 15, 13466-13473.

(1) Zeng, X. Q.; Beckers, H.; Willner, H. Photoisomerization of Matrix Isolated F2CS into Cis and Trans FCSF. Chem. Commun. 2009, 34, 5162-5164.